Simultaneous self-assembly of a cage-like silver(I) complex encapsulating an Ag6 neutral cluster core and carbon dioxide fixation
发布时间：2018-11-29
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- 发表刊物：
- CHEMICAL COMMUNICATIONS
- 刊物所在地：
- The Royal Society of Chemistry
- 关键字：
- carbon dioxide fixation, Ag6 neutral cluster core
- 摘要：
- A novel mixed-valent AgI/Ag0 Th-Ag34 cage was obtained by a one-pot ultrasonic reaction. In the shell of the cage, (CO3)2- anionis derived from atmospheric CO2 and adopts a rare l6 bridging mode to link the AgI ions. In the core of the cage, an unprecedented neutral metal cluster with six zero-valent silver atoms is encapsulated.
- 卷号：
- 47
- 页面范围：
- 1461-1463
- 是否译文：
- 否
- 发表时间：
- 2010-12-02
- 第一作者：
- 骆耿耿