发表刊物：InfoMat
摘要：Due to their unique photoelectric properties, nontoxic tin-based perovskites are emerging candidates for efficient near-infrared LEDs. However, the facile oxidation of Sn2+ and the rapid crystallization rate of tin-based perovskites result in suboptimal film quality, leading to inferior efficiencies of tin-based perovskite light-emitting diodes (Pero-LEDs). In this study, we investigate the influence of commonly used solvents on the quality of the CsSnI3 films. Remarkably, DMSO exhibits a stronger interaction with SnI2, forming a stable intermediate phase of SnI23DMSO. This intermediate effectively inhibits the oxidation of Sn2+ and slows down the crystallization rate, bringing in lower defect state density and higher photoluminescence quantum yield of the prepared perovskite films. Consequently, the corresponding Pero-LEDs achieve a maximum external quantum efficiency (EQE) of 5.6%, among the most efficient near-infrared Pero-LEDs. In addition, the device processes ultra-low efficiency roll-off and high reproducibility. Our research underscores the crucial role of solvent-perovskite coordination in determining film quality. These findings offer valuable guidance for screening solvents to prepare highly efficient and stable tin-based perovskites.
论文类型：期刊论文
学科门类：工学
一级学科：材料科学与工程
卷号：6
期号：5
页面范围：e12537
ISSN号：2567-3165
是否译文：否
发表时间：2024-02-01
收录刊物：SCI
DOI码：10.1002/inf2.12537
影响因子：22.7
发布期刊链接：https://onlinelibrary.wiley.com/doi/10.1002/inf2.12537
