Characterization of a well-resolved acyclic methanol(water)5 heterohexamer in the solid state
发布时间：2018-11-29
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- 发表刊物：
- INORGANIC CHEMISTRY COMMUNICATIONS
- 刊物所在地：
- ELSEVIER
- 关键字：
- Silver(I); 1,3-bis(4-pyridyl)propane; 5-sulfosalicylic acid; Water pentamer; Methanol-water binary cluster; DFT calculation
- 摘要：
- A novel (CH3OH)(H2O)5 binary cluster is trapped in a photoluminescent silver(I) coordination polymeric host, [Ag2(bpp)2(H2O)(ssa)•4H2O•CH3OH]n (1, bpp = 1,3-bis(4-pyridyl)propane, H2ssa = 5-sulfosalicylic acid). The heterohexamer can be viewed as either a D5 water pentamer with a dangling methanol molecule or a combination of D4 tetrameric water and methanol-water heterodimer. This well-resolved heterohexamer may behave as a useful model helping us to further understand phase behavior of binary methanol-water system. The luminescent behavior of 1 was also discussed.
- 期号：
- 17
- 页面范围：
- 108-112
- 是否译文：
- 否
- 发表时间：
- 2010-11-02
- 第一作者：
- 戴劲草,彭程,赵青华,李东旭,骆耿耿