Direct observation of conformational change of adipate dianions encapsulated in water clusters
发布时间：2018-11-29
点击次数：
- 发表刊物：
- CRYSTENGCOMM
- 刊物所在地：
- Royal Society of Chemistry
- 摘要：
- Two novel hydrated adipate dianions including (adip)aaa?(H2O)16 and (adip)gag?(H2O)20 (adip = dianion of adipic acid, aaa = anti–anti–anti and gag = gauche–anti–gauche) were observed in two silver-based cationic hosts. They not only reveal the precise arrangement of water clusters around the carboxylate groups and aliphatic chains of adipate dianions, but show the conformational change of adipate dianions in water clusters, for the first time.
- 页面范围：
- 5377-5380
- 字数：
- 250000000
- 是否译文：
- 否
- 发表时间：
- 2011-12-08
- 第一作者：
- 戴劲草,吴季怀,骆耿耿